Mononitration of durene

Reaction conditions under which the nitration of durene give predominantly, and in high yield, mononitrodurene (I), rather than dinitrodurene were found. The nitrating agent was No2+RF6-. Nitration with nitrosulfuric acid also gave mononitrodurene; however, byproducts such as 2.3.5.6-Me4C6HCH2C6H2Me3-2,4,5, were also formed. The NO2 PF6- gave an intermediate additional compound with durene. The reaction carried out with 3.6-dideuterodurene in D2O shows no isotope effect

Broken symmetry, excitons, gapless modes and topological excitations in Trilayer Quantum Hall systems

We study the interlayer coherent incompressible phase in Trilayer Quantum Hall systems (TLQH) at total filling factor $\nu_{T}=1$ from three approaches: Mutual Composite Fermion (MCF), Composite Boson (CB) and wavefunction approach. Just like in Bilayer Quantum Hall system, CB approach is superior than MCF approach in studying TLQH with broken symmetry. The Hall and Hall drag resistivities are found to be quantized at $h/e^{2}$. Two neutral gapless modes with linear dispersion relations are identified and the ratio of the two velocities is close to $\sqrt{3}$. The novel excitation spectra are classified into two classes: Charge neutral bosonic 2-body bound states and Charge $\pm 1$ fermionic 3-body bound states. In general, there are two 2-body Kosterlize-Thouless (KT) transition temperatures and one 3-body KT transition. The Charge $\pm 1$ 3-body fermionic bound states may be the main dissipation source of transport measurements. The broken symmetry in terms of $SU(3)$ algebra is studied. The structure of excitons and their flowing patterns are given. The coupling between the two Goldstone modes may lead to the broadening in the zero-bias peak in the interlayer correlated tunnelings of the TLQH. Several interesting features unique to TLQH are outlined. Limitations of the CB approach are also pointed out.Comment: 10 pages, 3 figures, Final version to be published in Phys. Rev.

Illumination uniformity in endoscopic imaging

Standardised endoscopic digital images were taken and analysed using an image analysis software (National Instruments Vision Assistant version 7.1.1). The luminance plane was extracted and the pixel intensity distribution was determined along a horizontal line at the position of highest average intensity (centroid). The data was exported to MS Excel and the pixel intensity (y-axis) was plotted against pixel position (x-axis). A trendline using a 2nd order polynomial curve was fitted to each data set. The resultant equation for each curve was compared with equations obtained from other images taken under various illumination conditions and settings

Spin Susceptibility and Gap Structure of the Fractional-Statistics Gas

This paper establishes and tests procedures which can determine the electron energy gap of the high-temperature superconductors using the $t\!-\!J$ model with spinon and holon quasiparticles obeying fractional statistics. A simpler problem with similar physics, the spin susceptibility spectrum of the spin 1/2 fractional-statistics gas, is studied. Interactions with the density oscillations of the system substantially decrease the spin gap to a value of $(0.2 \pm 0.2)$ $\hbar \omega_c$, much less than the mean-field value of $\hbar\omega_c$. The lower few Landau levels remain visible, though broadened and shifted, in the spin susceptibility. As a check of the methods, the single-particle Green's function of the non-interacting Bose gas viewed in the fermionic representation, as computed by the same approximation scheme, agrees well with the exact results. The same mechanism would reduce the gap of the $t\!-\!J$ model without eliminating it.Comment: 35 pages, written in REVTeX, 16 figures available upon request from [email protected]

Simulations of a Scintillator Compton Gamma Imager for Safety and Security

We are designing an all-scintillator Compton gamma imager for use in security investigations and remediation actions involving radioactive threat material. To satisfy requirements for a rugged and portable instrument, we have chosen solid scintillator for the active volumes of both the scatter and absorber detectors. Using the BEAMnrc/EGSnrc Monte Carlo simulation package, we have constructed models using four different materials for the scatter detector: LaBr_3, NaI, CaF_2 and PVT. We have compared the detector performances using angular resolution, efficiency, and image resolution. We find that while PVT provides worse performance than that of the detectors based entirely on inorganic scintillators, all of the materials investigated for the scatter detector have the potential to provide performance adequate for our purposes.Comment: Revised text and figures, Presented at SORMA West 2008, Published in IEEE Transactions on Nuclear Scienc

Vortex lattices in the lowest Landau level for confined Bose-Einstein condensates

We present the results of numerical calculations of the groundstates of weakly-interacting Bose-Einstein condensates containing large numbers of vortices. Our calculations show that these groundstates appear to be close to uniform triangular vortex lattices. However, slight deviations from a uniform triangular lattice have dramatic consequences on the overall particle distribution. In particular, we demonstrate that the overall particle distribution averaged on a lengthscale large compared to the vortex lattice constant is well approximated by a Thomas-Fermi profile.Comment: 5 pages, 4 figure

Compositional nanodomain formation in hybrid formate perovskites

We report the synthesis and structural characterisation of three mixed-metal formate perovskite families [C(NH$_2$)$_3$]M$_{1-x}$Cu$_x$(HCOO)$_3$ (M = Mn, Zn, Mg). Using a combination of infrared spectroscopy, non-negative matrix factorization, and reverse Monte Carlo refinement, we show that the Mn- and Zn-containing compounds support compositional nanodomains resembling the polar nanoregions of conventional relaxor ferroelectrics. The M = Mg family exhibits a miscibility gap that we suggest reflects the limiting behaviour of nanodomain formation.Comment: 4 pages, 3 figure

Onset of Interlayer Phase Coherence in a Bilayer Two-Dimensional Electron System: Effect of Layer Density Imbalance

Tunneling and Coulomb drag are sensitive probes of spontaneous interlayer phase coherence in bilayer two-dimensional electron systems at total Landau level filling factor $\nu_T = 1$. We find that the phase boundary between the interlayer phase coherent state and the weakly-coupled compressible phase moves to larger layer separations as the electron density distribution in the bilayer is imbalanced. The critical layer separation increases quadratically with layer density difference.Comment: 4 pages, 3 figure